About This Project
Plastic waste is extremely durable and can be harmful to organisms and their ecosystems when not managed properly. While current recycling methods can efficiently process certain plastics, some common plastics are not recyclable. Switchable hydrophilicity solvents (SHS) change from biphasic to monophasic when exposed to CO2. I hypothesize that solvents with similar structures to plastics will separate plastic materials into base components more efficiently than current recycling methods.
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What is the context of this research?
Switchable hydrophilicity solvents (SHS) change from biphasic to monophasic when exposed to CO2, which allows for distinct separation between hydrophilic/hydrophobic material in packaging. SHS dimethylcyclohexylamine is currently used to process multilayer flexible packaging. Unfortunately, beyond this, not much work is being conducted on recycling plastics with these solvents.
This project aims to fill the gap in research by processing materials via three SHS. The hypothesis is that SHS will process materials with similar structures most efficiently.
What is the significance of this project?
Improving recycling processes is crucial as the amount of plastic waste is immense and has many repercussions for the planet. This experiment could contribute to streamlining pre-existing recycling procedures as well as finding a more efficient and inclusive recycling process (even if it is only part of the process). Many curbside recycling programs do not accept some of the most commonly used plastics such as polystyrene, polyvinyl chloride, and mixed plastics. If the procedure described in this experiment is functional, it could be used on a larger scale, thereby removing more plastics from the landfill. Additionally, the innovation of this research is in that most work with SHS are on the discovery of them over recycling plastics with them.
What are the goals of the project?
When all project materials are received, food waste multilayer flexible plastics (MFP), commonly seen in potato chip bags, will be separated using a known procedure. We will separate the MFP into its components using 99% dimethylcyclohexylamine switched with a CO2 bubbling system and analyze them with NMR and scanning electron microscopy (SEM) before and after SHS treatment. The analysis will reveal the purity of the final sample and how "good" the separation by SHS was. Then, the steps above will be repeated for four other materials. For materials other than MFP, three solvents will be tested (dimethylcyclohexylamine, dimethylbenzylamine, and2-(dibutylamino)ethanol).
Safety materials such as the respirator, cartridges, and gloves will be used to ensure that all people in the vicinity of the experiment will be safe from the solvents, which can be harmful if they make contact with skin or eyes.
The CO2 aquarium bubbling system is crucial as it is what will cause the switch in the solvent that actually processes the plastics. The three solvents (dimethylcyclohexylamine, dimethylbenzylamine, and 2-(dibutylamino)ethanol) are the basis of the project, and therefore are absolutely necessary to the project.
The centrifugation is necessary to increase the separation speed of some of the layers of the multilayer flexible plastics from one another for individual analysis.
Finally, the local scanning electron (SEM) facility has a facility fee, and SEM is key to assessing the efficiency of the separation. The NMR facility runs without a fee, so no funding is required for this analytical method.
Between September 2019 and March 2020, the materials will be obtained and the procedure recycling multilayer flexible packaging will be completed. From March 2020 to December 2020, we will use 3 different solvents to attempt to recycle common, unrecyclable plastics.
The project takes place over a long time because, as a high school student conducting this project at school, I have many time limitations.
Oct 15, 2019
Nov 13, 2019
Mar 31, 2020
Complete MFP recycling procedure
Jun 30, 2020
Complete plastic recycling with DMCHA solvent
Oct 31, 2020
Complete plastic recycling with DMBA solvent
Meet the Team
I am a junior at Princeton High School taking a research course that allows students to design and execute their own research project. Science and math have always been my favorite subjects in school. I am especially passionate about chemistry as it explains the minutia of how everything around us works. Materials science is a more recent passion of mine because of its practical applications. Because there is more and more concern about humans' impact on the planet, I am interested in how my two favorite science subjects can be used to contribute to saving our planet.
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For further and more detailed information on this project, please click the link to the full proposal:
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